Name | Terthiophene |
Chemical Formula | C12H8S3 |
Molar Mass | 248.38 g/mol |
Appearance | Yellow - orange solid |
Melting Point | 112 - 114 °C |
Boiling Point | 377 °C |
Solubility In Water | Insoluble |
Solubility In Organic Solvents | Soluble in common organic solvents like chloroform, toluene |
Density | 1.31 g/cm³ |
Uv Vis Absorption | Absorbs in the visible region, typically around 400 - 500 nm |
Electrical Conductivity | Semi - conductive |
Crystal Structure | Monoclinic |
What is the chemical structure of Terthiophene?
The terthiophene is one of the organic compounds with a unique chemical structure. This compound is composed of thiophene as the basic unit and three thiophene rings connected in a specific way.
The thiophene ring has a five-membered heterocyclic structure, which contains a sulfur atom. In terthiophene, three thiophene rings are conjugated to each other to form a linear conjugate system. This conjugate structure endows terthiophene with many special physical and chemical properties.
Its conjugate system allows electrons to move relatively freely within the molecule, which in turn affects the electron cloud distribution and energy level structure of the molecule. In this way, terthiophene exhibits unique properties in the field of optoelectronics, such as good electron transport capacity and optical absorption properties.
From the perspective of bonding, thiophene rings are connected by carbon-carbon bonds, forming a stable molecular skeleton. The properties and spatial arrangement of these bonds play an important role in the shape, rigidity and stability of the molecular whole.
In short, the chemical structure of terthiophene is characterized by the connection of three conjugated thiophene rings. This structure lays the foundation for its applications in materials science, organic electronics and other fields.
What are the main application fields of Terthiophene?
Terthiophene is also an organic compound, which has important uses in many fields.
First, in the field of optoelectronic materials, terthiophene compounds exhibit good photoelectric properties due to their unique conjugate structure. Often a key component of organic semiconductor materials, in organic field effect transistors (OFETs), it can improve carrier mobility, improve device performance, and make electronic devices more efficient and sensitive. In organic Light Emitting Diodes (OLEDs), it can be used as a light-emitting layer material to emit light of a specific color, help achieve full-color display, etc., and promote the development of display technology.
Second, in the field of sensors, terthiophene can respond to specific substances or physical quantities. Due to the correlation between its structure and electrical properties, it can sense changes in gases, ions, etc. in the environment. For example, sensors that are sensitive to certain harmful gases can be designed. When harmful gases are present, the electrical properties of terthiophene materials change, thereby detecting gases, which is of great significance in environmental monitoring, food safety testing, etc.
Third, in the field of energy storage, in energy storage systems such as lithium-ion batteries, terthiophene derivatives can be used as additives or active components of electrode materials. By optimizing the structure and properties of electrode materials, improving the charging and discharging efficiency and cycle stability of batteries, it is quite helpful for the research and development of new high-efficiency energy storage devices.
Fourth, in the field of organic synthesis, terthiophene, as an important synthetic block, can construct complex organic molecular structures through various chemical reactions. Chemists can modify it by functionalization to expand its reactivity and prepare organic compounds with specific functions, providing rich synthetic intermediates for pharmaceutical chemistry, materials chemistry and other fields.
What are the physical properties of Terthiophene?
Tethiophene is a class of sulfur-containing aromatic heterocyclic compounds. It has unique physical properties and has attracted much attention in the fields of scientific research and industry.
In terms of appearance, Tethiophene is mostly a crystalline solid under normal conditions, with a color ranging from white to light yellow, and the morphology is often fine crystals. The texture is uniform and the appearance has a certain luster. This appearance characteristic affects its mixing and dispersion with other substances in many application scenarios.
In terms of melting point, the melting point of different structures of Tethiophene is different, about tens of degrees Celsius to hundreds of tens of degrees Celsius. The characteristics of the melting point are controlled by the conditions of its melting processing in the material preparation process. If the temperature is not appropriate, the material properties may be deteriorated.
In terms of solubility, terthiophene exhibits a certain solubility in common organic solvents such as chloroform, dichloromethane, toluene, etc. However, in water, due to its hydrophobicity, the solubility is extremely low. This difference in solubility is of great significance to the choice of reaction solvent during chemical synthesis, which is related to the smooth progress of the reaction and the separation and purification of the product.
Electrical properties are also a major feature of terthiophene. It has a conjugated structure and good electron delocalization, so it has certain semiconductor properties. With this property, terthiophene and its derivatives are widely used in organic semiconductor devices such as organic field effect transistors, organic Light Emitting Diodes, etc., which can effectively transport and regulate charges and improve the photoelectric performance of devices.
Thermal stability should also not be ignored. Over a certain temperature range, the structure of terthiophene is stable and the performance does not change significantly. However, if the temperature exceeds a certain threshold, the structure may be damaged and the performance will be damaged. This characteristic is a key consideration in high-temperature processes or applications in high-temperature environments, and careful temperature control is required to ensure stable material properties.
What are the synthesis methods of Terthiophene?
There are various ways to synthesize pentathiophene. One is a chemical synthesis method, and the common one is a coupling reaction. Halogenated thiophene is used as the starting material and under the action of an appropriate catalyst, the coupling reaction is carried out. For example, the Stille coupling reaction catalyzed by palladium, the halogenated thiophene meets the organotin reagent, and under the guidance of palladium catalyst, the carbon-carbon bond is linked to gradually construct the skeleton of pentathiophene. This reaction condition is relatively mild and requires substrate selectivity. However, it can precisely control the reaction check point and improve the purity of the product.
There is also a Suzuki coupling reaction. Halogenated thiophene interacts with arylboronic acid in the presence of a base and a palladium catalyst. This reaction is convenient to operate and easy to obtain raw materials. It is widely used in the field of organic synthesis. The synthesis of pentathiophene is also often used in this way.
Furthermore, the electrochemical synthesis method is also the way to synthesize pentathiophene. In an electrolytic cell, an electrolyte containing thiophene derivatives is used to electrochemically polymerize thiophene units on the electrode surface by controlling the electrode potential, current and other parameters. This method is green and environmentally friendly, does not require many additional reagents, and can be carried out at room temperature and pressure. It can effectively avoid the influence of harsh conditions such as high temperature and high pressure on the structure of the product. However, the reaction rate may be slower than that of the chemical synthesis method, and the reaction parameters need to be fine-tuned.
In addition, there is a template synthesis method. A suitable template molecule is selected to interact with thiophene monomer to form a specific assembly structure. With the guidance of the template, thiophene monomer is polymerized to form pentathiophene. This method can precisely control the morphology and size of the product, which is quite advantageous in the preparation of special structures of pentathiophene.
What is the price range of Terthiophene in the market?
It is difficult to determine the price of terthiophene in today's market. The price of terthiophene often changes with time, place, and supply and demand. In the past, when the market changed, the price of all kinds of materials changed according to the world conditions.
If you look at the approximate, the price of terthiophene may vary depending on the quality. The good one will be expensive; the second one will be slightly cheaper. And the amount of its production is also the key to the price. If the origin is rich and the output is plentiful, the supply in the city exceeds the demand, and the price may decline; conversely, if the source is scarce, there are many seekers, and the supply is in short supply, the price will rise.
Also, the price varies depending on the place where it is located. The prosperous capital is Dayi, where merchants and goods gather, logistics is convenient, and the price may be stable; however, in remote places, traffic is blocked, and transshipment is difficult, its price may increase. In addition, changes in the world situation, decrees, regulations, and tax adjustments can all affect the price of terthiophene.
Although it is difficult to determine the fixed price of its price, it is common sense that its price may fluctuate within a certain range. However, if you want to know the real-time accurate price, you should consult merchants, brokers, or look up the books of recent transactions in the city.