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What is the chemical structure of EDOT (3,4-ethylenedioxythiophene)?
EDOT (3,4-ethylenedioxythiophene) is an organic compound whose molecule contains a thiophene ring, and is connected by an ethylenedioxide bridge at the 3,4 positions of the thiophene ring. This structure endows it with unique electrical and chemical properties.
Looking at its chemical structure, the thiophene ring is a five-membered heterocycle and has aromatic properties. The structure is more stable due to the delocalized distribution of π electrons in the entire ring system. The sulfur atom of the thiophene ring has a lone pair of electrons, which can participate in chemical reactions and coordination, and has a great influence on the distribution of electron clouds and reactivity of compounds.
The ethylenedioxide bridge connected at the 3,4 positions is composed of two oxygen atoms and two methylene atoms. This bridge structure changes the electron cloud density distribution of the thiophene ring, making the electron cloud more uniformly dispersed. The ethylene dioxide bridge enhances molecular coplanarity, facilitates intermolecular electron transport, enhances intermolecular interaction, and has a significant impact on the electrical properties of materials.
The chemical structure characteristics of EDOT make it widely used in the field of conductive polymers. It is often used as a monomer through chemical or electrochemical polymerization to generate poly-3,4-ethylenedioxythiophene (PEDOT). Due to the structural characteristics of EDOT, PEDOT has high electrical conductivity, excellent environmental stability and good film-forming properties. It has broad application prospects in organic electronic devices such as organic Light Emitting Diodes, solar cells and sensors.
What are the main application fields of EDOT (3,4-ethylenedioxythiophene)
EDOT (3,4-ethylenedioxythiophene) is useful in many fields.
EDOT is very useful in the synthesis of conductive polymers. When it meets an oxidizing agent, it can be polymerized into poly (3,4-ethylenedioxythiophene), or PEDOT. This polymer has good conductivity and stability, and is widely used in the field of electronic devices. For example, conductive inks can be used to print electronic circuits, making the fabrication of electronic devices more convenient and cost-effective. In organic Light Emitting Diodes (OLEDs), PEDOT can be used as a hole transport layer to help recombine electrons and holes, and improve the luminous efficiency and stability of OLEDs.
In the field of sensor manufacturing, EDOT is also indispensable. Because its conductivity is quite sensitive to changes in the surrounding environment, it can be used to make chemical sensors. For example, when detecting biomolecules, EDOT-based sensors can change the conductivity by interacting with biomolecules, so as to achieve sensitive detection of biomolecules. In environmental monitoring, it can detect harmful gases, heavy metal ions, etc., to escort environmental safety.
In the field of energy storage, EDOT also has performance. It is made into an electrode material for super capacitors. PEDOT-based electrode materials can provide high specific capacitance, good charge-discharge efficiency, and excellent cycle stability, which is expected to promote the application of super capacitors in portable electronic devices, electric vehicles, and other fields.
In addition, EDOT has also emerged in antistatic materials, electromagnetic shielding materials, etc. Due to its unique structure and properties, EDOT plays an important role in many fields. With the development of technology in the future, its application prospects will be broader.
What are the synthesis methods of EDOT (3,4-ethylenedioxythiophene)?
EDOT (3,4-ethylenedioxythiophene) is a key raw material in the field of organic synthesis, and its synthesis methods are diverse. The following is a detailed description of Jun:
First, the method of using thiophene as the initial raw material. Schilling thiophene and polyformaldehyde react under specific catalysts and suitable reaction conditions to generate 3-hydroxymethylthiophene. This step requires precise control of the reaction temperature and catalyst dosage to obtain the ideal yield. Subsequently, 3-hydroxymethylthiophene is converted into 3-chloromethylthiophene through dehydration reaction, which requires strict requirements on the anhydrous degree of the reaction environment. Next, 3-chloromethylthiophene reacts with ethylene glycol under the action of alkali to finally form EDOT. This route has a little more steps, but the raw materials are easy to obtain and have certain applications in industrial production.
Second, the method of using 1,4-dioxane as the starting material. 1,4-dioxane is first converted into 2,5-dihydroxy-1,4-dioxane through a specific reaction, and this reaction requires specific reagents and conditions. Then, 2,5-dihydroxy-1,4-dioxane reacts with sulfur and phosphorus reagents to generate 3,4-ethylenedioxythiophene-2,5-dione. Finally, EDOT is prepared by reduction reaction. This approach is relatively simple, the purity of the product is also high, but the cost of some raw materials is slightly higher.
Third, the electrochemical synthesis method. In a specific electrolyte solution, the compound containing thiophene structure is used as the raw material. By controlling the electrochemical parameters such as electrode potential and current density, an electrochemical reaction occurs on the electrode surface to directly generate EDOT. This method has the advantages of mild reaction conditions and environmental friendliness, but the equipment requirements are relatively high, and the large-scale production technology still needs to be improved.
The above synthesis methods have their own advantages and disadvantages. In practical application, the appropriate synthesis path should be carefully selected according to the specific needs, such as cost, purity, scale and other factors.
What are the characteristics of EDOT (3,4-ethylenedioxythiophene)?
EDOT (3,4-ethylenedioxythiophene) is an organic compound and is very important in the field of conductive polymers. It has the following characteristics:
First, its structure is unique. The molecule contains a thiophene ring, and the 3,4 positions are bridged by ethylenedioxythiophene. This structure endows it with good stability and conjugation. The conjugation system is conducive to electron delocalization, resulting in special electrical and optical properties of the compound.
Second, it is easy to polymerize. Due to the activity of thiophene rings, EDOT can be chemically oxidized or electrochemically polymerized to form conductive polymers, such as poly (3,4-ethylenedioxythiophene) or PEDOT. The polymer has high conductivity and environmental stability, and is widely used in electronic devices.
Third, excellent conductivity. The conductivity of the formed PEDOT can reach the range of 10 - 1000 S/cm, which is much higher than that of most insulating materials. This high conductivity makes PEDOT widely used in transparent conductive electrodes and organic electronic devices, such as transparent conductive coatings for flat panel displays.
Fourth, good environmental stability. EDOT and its polymers can resist oxidation and hydrolysis, and can exist stably in different environments for a long time. Taking PEDOT as an example, it can resist the erosion of oxygen and water vapor in the air and maintain stable electrical performance, which is particularly critical in outdoor electronic equipment, biosensors and other devices that need long-term stable operation.
Fifth, unique optical properties. EDOT polymers have specific absorption and emission characteristics in the visible region, and can present different colors. By changing the polymer structure and doping, its optical properties can be regulated and used in optoelectronic devices such as organic Light Emitting Diodes (OLEDs) and photodetectors.
What is the price range of EDOT (3,4-ethylenedioxythiophene) in the market?
The price of EDOT (3,4-ethylenedioxythiophene) in the market is difficult to determine. Its price fluctuates due to quality, quantity, supply and demand, and time and place.
Looking at the past market conditions, those with good quality and ordinary quantity, the price is about a few yuan to tens of yuan per gram. If you buy a lot, you may get a little discount. In case of changes in market conditions, such as scarcity of raw materials and sudden increase in demand, the price may fluctuate significantly.
If the origin of raw materials suddenly changes at a certain time, resulting in rare raw materials, the production of EDOT is blocked, and its price rises. On the contrary, if production capacity increases sharply and demand does not advance, the price may decline.
If you want to know the exact current price, you should consult chemical raw material suppliers, traders, or explore the price information of chemical product trading platforms. These ways can obtain real-time price information, which helps you understand the market situation and obtain a reasonable price.