Chemical Formula | C24H8N2O6 |
Molecular Weight | 428.33 g/mol |
Appearance | Red - violet solid |
Melting Point | >300 °C |
Solubility | Insoluble in water, soluble in some organic solvents like DMF, DMSO |
Absorption Maximum | Around 520 - 550 nm in solution |
Emission Maximum | Around 550 - 600 nm in solution |
Fluorescence Quantum Yield | Can be relatively high in some cases, e.g., up to 0.8 in certain solvents |
Thermal Stability | Good thermal stability up to high temperatures |
Crystal Structure | Typically forms planar, stacked structures in the solid state |
What is the chemical structure of Perylene-3,4:9, 10-tetracarboxydiimide?
Perylene - 3,4:9,10 - tetracarboxydiimide (Perylene - 3,4:9,10 - tetracarboxydiimide), its chemical structure is quite exquisite. In this structure, the core is a fused cyclic aromatic hydrocarbon structure, which is formed by fusing multiple benzene rings. It is just like the exquisite tenon-mortise structure of ancient times. The rings are interlocked and very stable.
At a specific position in its core structure, that is, at 3,4 and 9,10, there is a part connected to the tetracarboxydiimide. This part is like a treasure embedded on a solid foundation. In the structure of tetracarboxydiimide, the carboxyl group is dehydrated and condensed to form a diimide structure, which gives the compound its unique electronic properties and chemical activity.
From a holistic perspective, the structure of the compound combines the rigidity and conjugation characteristics of fused cyclic aromatics, as well as the reactivity and electronic regulation ability of the tetracarboxylic acid diimide part. Just like the layout of ancient military art, rigidity and softness complement each other. The fused cyclic aromatics part provides good electron delocalization, which makes the molecule have certain electrical conductivity and optical properties; while the tetracarboxylic acid diimide part can fine-tune the electron cloud distribution and solubility of the molecule by changing the substituent group, etc., just like a skilled craftsman carving utensils on demand, making it both practical and unique. Due to this structural property, Perrin-3,4:9,10-tetracarboxylamine has shown unique application potential in materials science, optoelectronics, and many other fields.
What are the main physical properties of Perylene-3,4:9, 10-tetracarboxydiimide?
Perylene-3,4:9,10-tetraformate diimide is one of the most distinctive organic compounds. Its main physical properties are as follows:
In terms of color state, this substance is often crystalline, and the color is mostly orange red to purple red. The color is bright, like the bright color of Dan sand, like the splendor of sunset. This bright color is derived from the special conjugate system in its molecular structure, and the light and color are fully displayed between electron transitions.
In terms of solubility, it has a certain solubility in common organic solvents such as chloroform and dichloromethane. However, in water, it is extremely insoluble, just like the insolubility of oil and water, because its molecules are non-polar and repel each other with polar water.
The melting point is quite high, generally above 300 degrees Celsius, just like the heat resistance of rock, it is not easy to melt after high temperature. This is due to the strong interaction between molecules, such as the accumulation of π - π , the molecules are closely connected, and it requires extremely high energy to melt.
Sublimation is also one of its characteristics. It can be sublimated under certain conditions, just like a butterfly breaking a cocoon. It is directly converted from a solid state to a gaseous state without a liquid state. This characteristic is often used in the process of separation and purification.
In addition, perylene-3,4:9,10-tetraformic acid diimide has good thermal stability, and its molecular structure is not easy to disintegrate in high temperature environments. It is like a rock standing in the wind and can withstand a considerable degree of thermal shock, so it has advantages in many application scenarios in high temperature environments. Its optical properties are also outstanding, and it has unique absorption and emission spectra. It has broad application prospects in the field of optoelectronics, such as fluorescent materials. It is like a shining pearl in the dark night, illuminating the development path of related fields.
Perylene-3,4:9, What are the applications of 10-tetracarboxydiimide?
Perylene - 3,4:9,10 - tetracarboxydiimide (perylene - 3,4:9,10 - tetracarboxydiimide) is widely used in various fields.
It has attracted much attention in the field of materials science. This compound has unique photoelectric properties and can be used to produce high-efficiency organic photovoltaic materials. Due to its stable structure and good light absorption, it can effectively absorb light energy and convert it into electrical energy. Therefore, it can be a key material in the research and development of solar cells, which is expected to improve the conversion efficiency of batteries and promote the development of renewable energy.
It also has outstanding performance in fluorescent probes. Its unique fluorescence properties and sensitivity to environmental changes can be used for the detection of specific substances in biological systems. For example, in the field of cell imaging, labeling biomolecules can clearly observe the physiological processes in cells, and help researchers to deeply explore the mysteries of cells, which is of great significance to biomedical research.
Furthermore, in the field of organic Light Emitting Diode (OLED), it can also show its skills. With its excellent luminous properties, it can be used as a luminous layer material to improve the luminous efficiency and color purity of OLEDs, make the image quality of display devices clearer and brighter, and promote the innovation of display technology.
In addition, in the field of sensors, because of its selective response to specific chemical substances, high-sensitivity sensors can be designed to detect environmental pollutants, harmful gases, etc., and play an important role in environmental protection and safety monitoring. All this shows the wide application of Perylene - 3, 4:9, 10 - tetracarboxydiimide and the broad prospects.
What are the synthetic methods of Perylene-3,4:9, 10-tetracarboxydiimide?
The synthesis method of Perylene - 3,4:9,10 - tetracarboxydiimide (perylene - 3,4:9,10 - tetracarboxydiimide) has been known for a long time and has a wide variety.
First, perylene tetracarboxydiimide and suitable amines are used as raw materials, and can be prepared by condensation reaction in a specific solvent. This process requires attention to the control of reaction temperature and time. If the temperature is too high, it may cause the product to decompose; if the time is too short, the reaction will not be complete. For example, in a classical preparation method, perylene tetramethylanhydride and amines are placed in a high-boiling organic solvent, such as N-methylpyrrolidone, and the reaction is promoted with a catalyst amount of alkali at high temperature. After separation and purification, the product can be obtained.
Second, the halogenated derivative of perylene is reacted with a nitrogen-containing nucleophilic reagent. Perylene is first halogenated to introduce halogen atoms, and then reacted with nucleophilic reagents under suitable conditions. This approach requires attention to the selectivity of the halogenation reaction to ensure that halogen atoms are introduced into the desired position. In the reaction, the type and dosage of solvents, bases have a great influence on the reaction process and product purity.
Third, by means of electrochemical synthesis. In a specific electrolyte system, perylene derivatives were used as raw materials, and parameters such as electrode potential and current density were controlled to achieve the synthesis of perylene-3,4:9,10-tetracarboxylic acid diimide. This method is relatively green and environmentally friendly, does not require the use of a large number of chemical reagents, but requires high equipment and harsh reaction conditions, and requires precise regulation of various electrochemical parameters.
Different synthesis methods have their own advantages and disadvantages. The appropriate method should be weighed according to actual needs, such as product purity, cost, reaction scale and other factors.
Perylene-3,4:9, What is the market outlook for 10-tetracarboxydiimide?
Perylene - 3,4:9,10 - tetracarboxydiimide (perylene - 3,4:9,10 - tetracarboxydiimide), this product in today's market prospects, it is worthy of further investigation.
In the field of Guanfu materials, its emerging potential is gradually emerging. Due to its unique photoelectric properties, the cover has great potential in organic optoelectronic devices. Such as organic Light Emitting Diode (OLED), perylene - 3,4:9,10 - tetracarboxylic acid diimide can be used as luminescent materials. With its excellent fluorescence quantum yield and high stability, OLED can present more gorgeous colors and higher luminous efficiency. Therefore, it is expected to win a place in the display technology market to meet consumers' needs for high definition and energy-saving displays.
In the field of solar cells, it can also show its skills. With good light absorption performance and charge transfer ability, it may improve the photoelectric conversion efficiency of solar cells. With the increasing global reliance on renewable energy, the solar cell market is booming. Perylene-3,4:9,10-tetracarboxylic acid diimide may be able to take advantage of this opportunity and get a piece of the pie.
However, its market expansion is not smooth. The complexity of the preparation process and the high cost are the previous problems. To apply on a large scale, we must find ways to simplify the process and reduce costs. And the market competition is fierce, and similar materials are constantly being introduced. Therefore, only by sharpening innovation and improving technology can we gain a firm foothold in the market, expand broader prospects, shine on the stage of materials, and inject new vitality into the development of related industries.