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What are the main uses of 8-hydroxyquinoline sulfate hydrate?
8-Hydroxyquinoline copper (a complex of basic copper carbonate and 8-hydroxyquinoline), its main uses are as follows:
In the agricultural field, it is an important fungicide. It can effectively inhibit many agricultural crop diseases, such as citrus canker disease. By spraying a drug containing 8-hydroxyquinoline copper on citrus trees rationally, a protective film can be formed on the surface of plants to hinder the invasion of pathogenic bacteria. At the same time, it can also interfere with the metabolic process of pathogenic bacteria and inhibit their growth and reproduction, thereby reducing the damage of canker disease to citrus fruits and leaves and improving citrus yield and quality. For cucumber downy mildew, 8-hydroxyquinoline copper can also play a good prevention and control effect. By contacting pathogens, it destroys its cell structure and function to achieve the purpose of disease prevention and control.
In industry, it can be used as a preservative. Adding 8-hydroxyquinoline copper to coatings, wood and other products can prevent microbial erosion of the product and prolong the service life of the product. For example, in wood preservative treatment, soaking the wood in a solution containing 8-hydroxyquinoline copper will infiltrate the interior of the wood, inhibit the growth of microorganisms inside the wood, avoid wood decay and mildew, and enhance the durability of wood in outdoor environments, making it widely used in buildings, bridges and other fields.
In the pharmaceutical industry, 8-hydroxyquinoline copper has certain antibacterial and antiviral activities. It can be used to prepare external drugs for diseases caused by some skin fungi, assist in the treatment of skin infection symptoms, and promote the healing of skin infection sites by inhibiting the growth of fungi.
In the field of chemical analysis, it can be used as a precipitant and color developer for metal ions. Since 8-hydroxyquinoline copper can react specifically with a variety of metal ions to generate complexes with specific colors and properties, it can be used for the identification and quantitative analysis of metal ions. For example, when analyzing the content of aluminum ions in water samples, the complex formed by the reaction of 8-hydroxyquinoline copper with aluminum ions has strong absorption at a specific wavelength, so that the concentration of aluminum ions can be accurately determined.
What are the physical properties of 8-hydroxyquinoline sulfate hydrate?
8-Hydroxyquinoline calcium borate oxalate hydrate is a unique chemical substance with several special physical properties.
Its appearance may be specific, common or crystalline, with regular crystal shape and a certain geometric shape. Viewed under a microscope, it can be seen that it is arranged in order, reflecting the internal atomic or molecular regular structure. This morphological feature is closely related to the intermolecular force and crystallization process.
The solubility of this substance has its own characteristics. It varies in specific solvents. In some organic solvents, it may exhibit limited solubility. Due to the interaction of polar and non-polar parts in the molecular structure, it is different from the intermolecular force of the solvent. The solubility in water may also be limited, because it is difficult for the molecular structure to form an effective interaction with water molecules, or only under certain conditions, such as changing temperature, pH value, etc., the solubility changes.
In terms of thermal stability, 8-hydroxyquinoline calcium borate oxalate hydrate is relatively stable within a certain temperature range. However, when the temperature rises to a certain value, the chemical bonds within the molecule may begin to break due to the increase of energy, triggering structural changes. Or cause decomposition reactions to occur and form other substances. This temperature threshold varies slightly due to subtle differences in the purity and crystal structure of the substance.
In addition, the substance may have certain optical properties. For example, under the irradiation of a specific wavelength of light, the intra-molecular electrons absorb energy transitions, and then release energy in the form of light, showing a fluorescence phenomenon. Its fluorescence emission spectrum has specific wavelength range and intensity characteristics, which can be used for analysis and detection and other fields.
Its density is also one of the important physical properties, depending on the way of molecular accumulation and relative molecular weight. The density affects its settlement and dispersion in different media. And the mechanical properties such as hardness of the substance are also of great significance for its processing and use in specific application scenarios.
Is the chemical property of 8-hydroxyquinoline sulfate hydrate stable?
8-Hydroxyquinoline calcium borate oxalate hydrate, which is a chemical compound. The stability of its chemical properties is related to many aspects of characteristics.
Looking at its structure, 8-hydroxyquinoline partially contains heteroatoms such as nitrogen and oxygen, which can combine with metal ions through coordination, thereby affecting the stability of the compound. As a metal ion, the coordination mode and bonding strength of calcium with ligands have a great influence on the overall stability.
Borate and oxalate also play an important role in it. Borate can participate in the formation of multiple coordination structures and enhance the interaction within the compound; oxalate can further stabilize the coordination environment of metal ions through chelation effect.
From the perspective of reactivity, if there are substances that can react with the compound in the environment, such as acidic or basic substances, its stability may be affected. In an acidic environment, some coordination bonds may be weakened by protonation, resulting in structural changes; in an alkaline environment, reactions such as ligand dissociation may also occur.
However, under usually mild conditions, if no specific reactants are present, the structure of this 8-hydroxyquinoline borate calcium oxalate hydrate can be maintained relatively stable. The interaction between its internal parts builds a relatively stable system. If there is no external interference, the chemical properties can be maintained for a certain period of time. However, under extreme conditions such as high temperature and strong acid and alkali, its stability will inevitably be damaged, or it will cause decomposition and structural rearrangement.
In summary, the stability of the compound is not absolute, but is influenced by environmental conditions and its own structural characteristics. Under suitable conditions, it can exhibit good stability; however, in unfavorable environments, the stability is uncertain.
What is the preparation method of 8-hydroxyquinoline sulfate hydrate?
To prepare 8-hydroxyquinoline borate copper ammonium oxalate hydrate, the method is as follows:
Prepare all the required things first, copper salt, boric acid, 8-hydroxyquinoline, ammonium oxalate and an appropriate amount of water. In a clean container, fill an appropriate amount of water, and then slowly add a certain amount of copper salt, with gentle stirring, so that it is fully dissolved in the water to form a uniform solution. The amount of this copper salt, when accurately weighed, should be in accordance with the predetermined formula ratio, and there should be no slight difference.
Next, the boric acid is also slowly poured into this solution, and the stirring is continued to make the boric acid gradually dissolve and blend with the copper salt solution. The addition of boric acid should be smooth, and the stirring should not be stopped, so as to promote its rapid and uniform dispersion in the solution.
After the mixture of copper salt and boric acid has stabilized, carefully add 8-hydroxyquinoline. When adding 8-hydroxyquinoline, pay attention to its speed. If it is too fast, it may cause the solution to overreact, and if it is too slow, it will take too much time, or it will affect the quality of the product. When adding, stir should be more gentle and continuous, so that 8-hydroxyquinoline can fully contact and react with the mixture of the first two.
After that, ammonium oxalate is prepared into a solution and slowly dropped into the above mixed system. The dripping process, such as drizzle moisturizing, should not be rushed, and at the same time, closely observe the changes of the solution, such as the change of color, the presence or absence of precipitation, etc. This dripping step has a great impact on the purity and structure of the final product, so it is necessary to operate with caution.
After the dripping is completed, it is still necessary to continue stirring for a period of time to allow the reaction in the system to proceed fully. Then, let the mixture stand at a suitable temperature and environment, so that the substances in it can slowly react and crystallize. This process requires patience and must not be disturbed frequently, so as not to destroy the formation of crystals.
When the crystallization is completed, carefully separate the crystal from the mother liquor, or use filtration or centrifugation, according to the actual situation. The resulting crystals are washed several times with an appropriate amount of solvent to remove the attached impurities. After washing, dry them at a suitable temperature to remove the moisture, and finally obtain 8-hydroxyquinoline borate copper oxalate ammonium hydrate. The whole process requires fine operation, accurate proportions, and appropriate environment, so that high-quality products can be prepared.
What are the precautions for the storage and transportation of 8-hydroxyquinoline sulfate hydrate?
8-Hydroxyquinoline aluminum (Alq3) is commonly used in the field of organic electroluminescent materials. There are indeed many points to be paid attention to when storing and transporting it. The details are as follows:
###Storage
1. ** Moisture-proof **: 8-Hydroxyquinoline aluminum is susceptible to moisture and deterioration, because the hydroxyl group in its chemical structure is easy to interact with water molecules, causing its performance to change. Therefore, it should be stored in a dry environment and can be placed in a dryer, and the desiccant needs to be replaced regularly to maintain drying efficiency. If it is humid in the south, it is necessary to strengthen moisture-proof measures, such as encapsulation with moisture-proof packaging materials.
2. ** Avoid light **: This compound is sensitive to light, and light will cause it to undergo photochemical reactions, resulting in structural changes and performance deterioration. It should be stored in a dark container such as a brown bottle, in a dark place, to avoid direct sunlight and strong artificial light for a long time.
3. ** Temperature is suitable **: Excessive temperature will accelerate the thermal movement of its molecules, causing changes in its physical and chemical properties; if the temperature is too low, it may affect the stability of its crystal form. Usually it should be stored in a refrigerated environment of 2-8 ° C. If there is no refrigeration condition, it should also be placed in a cool place, so that the ambient temperature does not exceed 30 ° C.
###Transportation
1. ** Packaging Stable **: Vulnerable to vibration and collision during transportation, so the packaging must be stable. First wrap with soft materials such as foam, cotton, etc., and then place it in a sturdy outer packaging box to prevent damage due to collision and extrusion.
2. ** Keep dry **: Even if there is packaging, the humidity of the transportation environment may still be affected. An appropriate amount of desiccant, such as silica gel desiccant, can be placed in the package to absorb water vapor that may enter.
3. ** Temperature control transportation **: If the distance is long and the time is long, pay attention to temperature control. Thermal insulation packaging can be used, and if necessary, it can be transported by refrigerated truck to ensure that the temperature during transportation is within an appropriate range, so as to avoid damage to product quality due to abnormal temperature.