Chemical Formula | C14H21NO |
Molecular Weight | 217.322 g/mol |
Appearance | Yellow - brown viscous liquid |
Boiling Point | Approx. 267 - 269 °C |
Melting Point | - 45 °C |
Flash Point | 137 °C |
Density | 0.996 g/cm³ (at 20 °C) |
Solubility In Water | Insoluble |
Solubility In Organic Solvents | Soluble in many organic solvents like ethanol, benzene |
Stability | Stable under normal conditions, may decompose on exposure to high heat or strong oxidizing agents |
What is the use of 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline
6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, which is widely used. In the industrial field, it is often used as an antioxidant for rubber. When rubber is used, it is susceptible to aging due to many factors such as heat, oxygen, ozone and mechanical stress, resulting in deterioration of its properties. And 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline can effectively inhibit the aging process of rubber by trapping free radicals and decomposing peroxides, which greatly prolongs the service life of rubber products. Rubber products such as tires, hoses, tapes, etc. rely on it to improve their anti-aging properties. < Br >
In the field of oil additives, it also has important uses. During the storage and use of oil products, precipitation and colloids will also be formed due to oxidation, which affects the quality and performance of oil products. 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline can be added to oil products to act as an antioxidant, inhibit oil oxidation, maintain good fluidity and stability of oil products, and ensure the normal operation of engines and other equipment.
In addition, it can also be used as an intermediate in the preparation of some fine chemical products. With its unique chemical structure, it can generate other compounds with specific properties through a series of chemical reactions, providing raw material support for the development of the fine chemical industry, and then applying it to coatings, inks, medicine, and many other fields to help optimize and improve the performance of products in these fields.
What are the physical properties of 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline
6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, this is an organic compound with unique physical properties.
Looking at its properties, at room temperature and pressure, it is mostly in the state of light yellow to brown viscous liquid. Its color is derived from the interaction between specific atoms and chemical bonds in the molecular structure, which causes it to selectively absorb visible light.
When it comes to the melting point, the melting point of this compound is quite low, about -20 ° C. Due to the weak intermolecular force, the molecule can be freed from the lattice and converted from a solid state to a liquid state without excessive energy. < Br >
In terms of boiling point, it is about 267-269 ° C. This boiling point value indicates that the intermolecular force is moderate, and a higher temperature is required to enable the molecule to have enough energy to overcome the interaction and escape from the liquid surface.
Solubility is also a key property. It is insoluble in water. Due to the large proportion of hydrophobic parts in the molecular structure, it cannot form an effective interaction with water molecules, and it is difficult to break the hydrogen bond between water molecules and integrate into it. However, it is soluble in many organic solvents, such as ethanol, ether, benzene, etc. This is because it can interact with organic solvent molecules through Van der Waals force 、π - π accumulation, etc., to achieve mutual solubility. < Br >
The density is about 0.97 to 0.98 g/cm ³, which is slightly smaller than that of water. This is due to the molecular structure and the type and arrangement of atoms. The relative mass distribution and spatial structure of molecules determine that the mass per unit volume is smaller than that of water.
In addition, the compound has a certain degree of volatility and will evaporate slowly in air. Due to its molecular energy distribution, some high-energy molecules can overcome the surface tension of the liquid and enter the gas phase.
In summary, the physical properties of 6-ethoxy-1, 2-dihydro-2, 2, 4-trimethylquinoline are determined by its unique molecular structure, and these properties are of great significance for its applications in chemical and materials fields.
What are the chemical properties of 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline
6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline is one of the organic compounds. Its chemical properties are quite unique, let me tell them one by one.
This compound has a certain stability. Under normal conditions, its molecular structure is relatively stable, and it will also show an active state in special chemical environments. In acidic media, due to the nitrogen heterocyclic structure in the molecule, the nitrogen atom can accept protons, which in turn positively charges the molecule, enhancing its chemical activity, or leading to a series of chemical reactions, such as nucleophilic substitution reactions.
Looking at its solubility, 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline has good solubility in organic solvents, such as ethanol, ether, benzene, etc. This is because the molecular structure of the compound has hydrophobic alkyl and aromatic ring structures, which are similar to the molecular forces of organic solvents, and follow the principle of "similar compatibility". However, the solubility in water is poor, because the polarity of the molecule as a whole is relatively small, it is difficult to form strong interactions with water molecules.
In terms of thermal stability, under moderate heating conditions, the compound can maintain structural integrity. However, when the temperature rises to a certain extent, the chemical bonds in the molecule may break due to sufficient energy. The ethoxy part of it may decompose first to form ethanol and corresponding quinoline derivatives. If the temperature continues to rise, the quinoline ring may also open the ring or undergo a rearrangement reaction, resulting in a complete change in the molecular structure.
In addition, the double bond in the 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline molecule endows it with certain unsaturation. This double bond can participate in addition reactions, such as addition with halogens, hydrogen halides and other reagents, so that the double bond can be converted into a single bond, enriching its chemical properties and reaction path.
What is the synthesis method of 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline
The synthesis method of 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, although the ancient book "Tiangong Kaiwu" does not directly record the synthesis method of this specific compound, the chemical process ideas contained in the book can be used for reference to derive its synthesis outline.
To synthesize this compound, or according to the conventional ideas of organic synthesis. First, the appropriate starting material needs to be found. According to its structure, or the appropriate substituent can be selected from the aniline and acetone compounds as starting materials.
If 2,6-dimethylaniline and acetylacetone are used as starting materials, the condensation reaction can be carried out first. In this condensation reaction, the two react according to the nucleophilic addition-elimination mechanism under appropriate acidic or basic catalysis conditions to form an intermediate.
Suppose that an acid is used as a catalyst, such as p-toluenesulfonic acid, under heating conditions, the amino nucleophilic of 2,6-dimethylaniline attacks the carbonyl carbon of acetylacetone, and then the proton is transferred, the hydroxyl group leaves, and an intermediate containing carbon-nitrogen double bonds is formed.
Then, the intermediate is etherified with ethanol. Under alkaline conditions, such as the presence of potassium carbonate, the appropriate position of the intermediate can be reacted with ethanol under heating conditions, and the ethoxy group of ethanol replaces the hydrogen atom in the corresponding position. After these two main reactions, 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline can be synthesized.
Although this specific synthesis path is not detailed in "Tiangong Kai", the wisdom of the transformation of various substances in the book can inspire our generation to explore organic synthesis strategies to achieve the synthesis of this compound.
6-Ethoxy-1,2-dihydro-2,2, 4-trimethylquinoline What are the safety precautions?
6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinoline, this is an organic compound. Regarding its safety precautions, it is necessary to pay attention in detail.
First, this substance is chemically active, and it is necessary to strictly follow the experimental procedures when operating. If it is an experimental scene, it is necessary to read the relevant chemical safety technical instructions carefully in advance, and be familiar with its physical and chemical properties, such as melting point, boiling point, solubility, etc., in order to properly deal with various conditions.
Second, this compound may be toxic. When exposed, be sure to take protective measures. For hand protection, it is recommended to wear chemical protective gloves to prevent skin contact and absorption poisoning; for face protection, a protective mask should be worn to prevent it from splashing into the eyes or touching the skin of the face. It is crucial to operate in a well-ventilated place. If it is in a laboratory, it should be carried out in a fume hood, which can effectively avoid inhaling its volatile gaseous substances, which may irritate the respiratory tract or even cause more serious health problems.
Third, when storing, be careful. Store in a cool, dry and well-ventilated place, away from ignition and oxidants. Because of its chemical properties or exposure to open flames, hot topics pose a risk of combustion, contact with oxidants or cause violent reactions, it needs to be stored strictly separately, and it should be clearly labeled, indicating its name, characteristics and hazards and other key information for access and management.
Fourth, if you come into contact accidentally, you need to take the correct emergency treatment measures immediately. If you come into contact with the skin, you should immediately rinse with a large amount of flowing water, and then seek medical attention as appropriate; if you splash into the eyes, you should quickly rinse the eyes with a large amount of water and go to the hospital as soon as possible; if you inhale accidentally, you should immediately move to a place with fresh air, keep the respiratory tract unobstructed, and if necessary, perform artificial respiration and send to the hospital for first aid.
In short, the treatment of 6-ethoxy-1,2-dihydro-2,2,4-trimethylquinoline must not be taken lightly, from operation, protection, storage to emergency treatment, to ensure safety.